Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor
In this study, biodiesel was synthesized from a reaction of waste cooking oil (WCO) and methanol in the presence of catalyst which was derived from chicken bone and coconut residue in a packed bed reactor. Calcium oxide (CaO) was extracted from calcined chicken bone and nano-crystal cellulose (NCC)...
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| Format: | Article |
| Language: | English English |
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Elsevier Ltd
2020
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| Online Access: | http://irep.iium.edu.my/82217/1/82217_Biodiesel%20production%20from%20waste%20cooking%20oil%20using%20calcium%20oxide_full%20text.pdf http://irep.iium.edu.my/82217/2/82217_Biodiesel%20production%20from%20waste%20cooking%20oil%20using%20calcium%20oxide_scopus.pdf |
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| author | Zik, Nor Azyan Farrah Adila Sulaiman, Sarina Jamal, Parveen |
| author_facet | Zik, Nor Azyan Farrah Adila Sulaiman, Sarina Jamal, Parveen |
| author_sort | Zik, Nor Azyan Farrah Adila |
| collection | IIUM |
| description | In this study, biodiesel was synthesized from a reaction of waste cooking oil (WCO) and methanol in the presence of catalyst which was derived from chicken bone and coconut residue in a packed bed reactor. Calcium oxide (CaO) was extracted from calcined chicken bone and nano-crystal cellulose (NCC) was isolated from coconut residue by acid hydrolyzed and were supported with polyvinyl alcohol (PVA). The catalyst was analyzed using Fourier transform infrared (FTIR), Field emission scanning electron microscopy (FESEM), Thermogravimetric analysis (TGA) and X-ray diffraction (XRD) to study its elemental composition and surface morphology. The parameters used for the reaction were optimized by Design of Experiment (DOE) using Central Composite Design (CCD) to maximize the biodiesel yield. The maximum yield of 98.40% was obtained at optimum temperature, methanol to oil and catalyst loading of 65 °C, 6:1 and 0.5 wt%, respectively. Investigation on the kinetic of the reaction specified that the reaction followed pseudo first order reaction with k-value ranged from 0.0092 min−1 to 0.0151 cm−1 and Thiele modulus was less than 2. The activation energy Ea for the transesterification reaction was 45.72 kJ/mol. |
| first_indexed | 2024-03-06T00:49:21Z |
| format | Article |
| id | oai:generic.eprints.org:82217 |
| institution | International Islamic University Malaysia |
| language | English English |
| last_indexed | 2024-03-06T00:49:21Z |
| publishDate | 2020 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | oai:generic.eprints.org:822172021-01-05T02:58:29Z http://irep.iium.edu.my/82217/ Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor Zik, Nor Azyan Farrah Adila Sulaiman, Sarina Jamal, Parveen T Technology (General) TP248.13 Biotechnology In this study, biodiesel was synthesized from a reaction of waste cooking oil (WCO) and methanol in the presence of catalyst which was derived from chicken bone and coconut residue in a packed bed reactor. Calcium oxide (CaO) was extracted from calcined chicken bone and nano-crystal cellulose (NCC) was isolated from coconut residue by acid hydrolyzed and were supported with polyvinyl alcohol (PVA). The catalyst was analyzed using Fourier transform infrared (FTIR), Field emission scanning electron microscopy (FESEM), Thermogravimetric analysis (TGA) and X-ray diffraction (XRD) to study its elemental composition and surface morphology. The parameters used for the reaction were optimized by Design of Experiment (DOE) using Central Composite Design (CCD) to maximize the biodiesel yield. The maximum yield of 98.40% was obtained at optimum temperature, methanol to oil and catalyst loading of 65 °C, 6:1 and 0.5 wt%, respectively. Investigation on the kinetic of the reaction specified that the reaction followed pseudo first order reaction with k-value ranged from 0.0092 min−1 to 0.0151 cm−1 and Thiele modulus was less than 2. The activation energy Ea for the transesterification reaction was 45.72 kJ/mol. Elsevier Ltd 2020-08 Article PeerReviewed application/pdf en http://irep.iium.edu.my/82217/1/82217_Biodiesel%20production%20from%20waste%20cooking%20oil%20using%20calcium%20oxide_full%20text.pdf application/pdf en http://irep.iium.edu.my/82217/2/82217_Biodiesel%20production%20from%20waste%20cooking%20oil%20using%20calcium%20oxide_scopus.pdf Zik, Nor Azyan Farrah Adila and Sulaiman, Sarina and Jamal, Parveen (2020) Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor. Renewable Energy, 155. pp. 267-277. ISSN 0960-1481 https://www.sciencedirect.com/science/article/abs/pii/S0960148120304778 10.1016/j.renene.2020.03.144 |
| spellingShingle | T Technology (General) TP248.13 Biotechnology Zik, Nor Azyan Farrah Adila Sulaiman, Sarina Jamal, Parveen Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor |
| title | Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor |
| title_full | Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor |
| title_fullStr | Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor |
| title_full_unstemmed | Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor |
| title_short | Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor |
| title_sort | biodiesel production from waste cooking oil using calcium oxide nanocrystal cellulose polyvinyl alcohol catalyst in a packed bed reactor |
| topic | T Technology (General) TP248.13 Biotechnology |
| url | http://irep.iium.edu.my/82217/1/82217_Biodiesel%20production%20from%20waste%20cooking%20oil%20using%20calcium%20oxide_full%20text.pdf http://irep.iium.edu.my/82217/2/82217_Biodiesel%20production%20from%20waste%20cooking%20oil%20using%20calcium%20oxide_scopus.pdf |
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