STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2

<p>Photoreduction of Cu(II) ion in the solution in the presence of UV light and TiO2 photocatalyst has been studied, in which the influences of reaction time, photocatalyst mass, concentration of Cu(II), and solution pH on the effectiveness of the reduction have also been evaluated. Photoreduc...

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Hoofdauteur: , Endang Tri Wahyuni, Mudasir, and Nurul Hidayat Aprilita
Formaat: Artikel
Gepubliceerd in: [Yogyakarta] : Fak. MIPA Universitas Gadjah Mada 2007
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author , Endang Tri Wahyuni, Mudasir, and Nurul Hidayat Aprilita
author_facet , Endang Tri Wahyuni, Mudasir, and Nurul Hidayat Aprilita
author_sort , Endang Tri Wahyuni, Mudasir, and Nurul Hidayat Aprilita
collection UGM
description <p>Photoreduction of Cu(II) ion in the solution in the presence of UV light and TiO2 photocatalyst has been studied, in which the influences of reaction time, photocatalyst mass, concentration of Cu(II), and solution pH on the effectiveness of the reduction have also been evaluated. Photoreduction was carried out by batch system in a closed reactor equipped with UV lamp having wavelength 300-400nm. The research results indicated that the presence of TiO2 could improve the photoreduction of Cu(II) ion into Cu metal deposited on the TiO2 surface. The improvement was proportional with the increase of TO2 mass, but no improvement was observed when the mass was further increased. The photoreduction increased as the reaction time was extended, but further extension gave no different effect. Increasing pH from 1-5 could enhance of Cu(II) reduction, and further increase of pH from 5-14 could transfer all of the ions from the solution due to precipitate of Cu(OH)2. The photoreduction enhanced with the increase of the initial concentration of Cu(II) but the photoreduction declined when the initial concentrations were further increased. The highest photoreduction of Cu(II) was reached, ca 20%, when 50 ml of Cu(II) 10ppm at pH 3 with 20 mg TiO2 for 24h of the reaction time, was employed. The effectiveness of Cu(II) photoreduction obtained was still low, and so improvement, i.e. by addition of organic acid as reducing agent is suggested.</p>
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spelling oai:generic.eprints.org:939552014-11-28T07:36:12Z https://repository.ugm.ac.id/93955/ STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2 , Endang Tri Wahyuni, Mudasir, and Nurul Hidayat Aprilita <p>Photoreduction of Cu(II) ion in the solution in the presence of UV light and TiO2 photocatalyst has been studied, in which the influences of reaction time, photocatalyst mass, concentration of Cu(II), and solution pH on the effectiveness of the reduction have also been evaluated. Photoreduction was carried out by batch system in a closed reactor equipped with UV lamp having wavelength 300-400nm. The research results indicated that the presence of TiO2 could improve the photoreduction of Cu(II) ion into Cu metal deposited on the TiO2 surface. The improvement was proportional with the increase of TO2 mass, but no improvement was observed when the mass was further increased. The photoreduction increased as the reaction time was extended, but further extension gave no different effect. Increasing pH from 1-5 could enhance of Cu(II) reduction, and further increase of pH from 5-14 could transfer all of the ions from the solution due to precipitate of Cu(OH)2. The photoreduction enhanced with the increase of the initial concentration of Cu(II) but the photoreduction declined when the initial concentrations were further increased. The highest photoreduction of Cu(II) was reached, ca 20%, when 50 ml of Cu(II) 10ppm at pH 3 with 20 mg TiO2 for 24h of the reaction time, was employed. The effectiveness of Cu(II) photoreduction obtained was still low, and so improvement, i.e. by addition of organic acid as reducing agent is suggested.</p> [Yogyakarta] : Fak. MIPA Universitas Gadjah Mada 2007 Article NonPeerReviewed , Endang Tri Wahyuni, Mudasir, and Nurul Hidayat Aprilita (2007) STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2. text. http://repository.ugm.ac.id/digitasi/index.php?module=cari_hasil_full&idbuku=1754
spellingShingle , Endang Tri Wahyuni, Mudasir, and Nurul Hidayat Aprilita
STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2
title STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2
title_full STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2
title_fullStr STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2
title_full_unstemmed STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2
title_short STUDY ON PHOTOCATALYTIC REDUCTION OF CU(II) IONS BY UV LIGHT AND TiO2
title_sort study on photocatalytic reduction of cu ii ions by uv light and tio2
work_keys_str_mv AT endangtriwahyunimudasirandnurulhidayataprilita studyonphotocatalyticreductionofcuiiionsbyuvlightandtio2