REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT

<p>Tannins extracted from the mangrove barks of Rhizophora apiculata species were modified into tannins-based adsorbent (TBA) by using formaldehyde in the basic solution of ammonia. The produced adsorbent showed high efficiency in removal of Cu2+ from the aqueous solution. Effect of adsorption...

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Yazar: , C.W. Oo, and K. Jain
Materyal Türü: Makale
Baskı/Yayın Bilgisi: [Yogyakarta] : Fak. MIPA Universitas Gadjah Mada 2007
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author , C.W. Oo, and K. Jain
author_facet , C.W. Oo, and K. Jain
author_sort , C.W. Oo, and K. Jain
collection UGM
description <p>Tannins extracted from the mangrove barks of Rhizophora apiculata species were modified into tannins-based adsorbent (TBA) by using formaldehyde in the basic solution of ammonia. The produced adsorbent showed high efficiency in removal of Cu2+ from the aqueous solution. Effect of adsorption parameters like initial adsorption pH, initial desorption pH and initial Cu2+ concentration were studied in batch experiments. The optimum adsorption pH of Cu2+ was at pH 7.0 with an adsorption percentage of 96.20%. Meanwhile, 82.68% of Cu2+ was desorbed from the loaded TBA at the initial pH of 4.0, which was the optimum desorption pH. Non-linear regression analysis was conducted to determine the fitness of Langmuir, Freundlich, Sips and Dubinin-Raduskhevich (D-R) isotherms to the experimental data at equilibrium. TBA showed high monolayer adsorption capacity of 17.41 mg of Cu2+/gram of adsorbent. Mean energy of adsorption, E calculated from D-R isotherm showed that adsorption of Cu2+ on TBA followed ion-exchange mechanism.</p>
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spelling oai:generic.eprints.org:939932014-11-28T07:36:11Z https://repository.ugm.ac.id/93993/ REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT , C.W. Oo, and K. Jain <p>Tannins extracted from the mangrove barks of Rhizophora apiculata species were modified into tannins-based adsorbent (TBA) by using formaldehyde in the basic solution of ammonia. The produced adsorbent showed high efficiency in removal of Cu2+ from the aqueous solution. Effect of adsorption parameters like initial adsorption pH, initial desorption pH and initial Cu2+ concentration were studied in batch experiments. The optimum adsorption pH of Cu2+ was at pH 7.0 with an adsorption percentage of 96.20%. Meanwhile, 82.68% of Cu2+ was desorbed from the loaded TBA at the initial pH of 4.0, which was the optimum desorption pH. Non-linear regression analysis was conducted to determine the fitness of Langmuir, Freundlich, Sips and Dubinin-Raduskhevich (D-R) isotherms to the experimental data at equilibrium. TBA showed high monolayer adsorption capacity of 17.41 mg of Cu2+/gram of adsorbent. Mean energy of adsorption, E calculated from D-R isotherm showed that adsorption of Cu2+ on TBA followed ion-exchange mechanism.</p> [Yogyakarta] : Fak. MIPA Universitas Gadjah Mada 2007 Article NonPeerReviewed , C.W. Oo, and K. Jain (2007) REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT. text. http://repository.ugm.ac.id/digitasi/index.php?module=cari_hasil_full&idbuku=1792
spellingShingle , C.W. Oo, and K. Jain
REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT
title REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT
title_full REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT
title_fullStr REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT
title_full_unstemmed REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT
title_short REMOVAL OF Cu2+ FROM AQUEOUS SOLUTION BY RHIZOPHORA APICULATA MANGROVE TANNINS-BASED ADSORBENT
title_sort removal of cu2 from aqueous solution by rhizophora apiculata mangrove tannins based adsorbent
work_keys_str_mv AT cwooandkjain removalofcu2fromaqueoussolutionbyrhizophoraapiculatamangrovetanninsbasedadsorbent