SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR
<p>Synthesis of 3-(3-allyl-4-hydroxy-5-methoxy phenyl)-1-phenyl prop-2-en-1-one from vanillin and its potentially application to the development of cyanide and fluoride anion sensor has been investigated. This compound has been synthesized via O-allylation reaction of vanillin (1) produced 4-a...
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| Format: | Article |
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[Yogyakarta] : Chemistry Departement Universitas Gadjah Mada
2010
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| _version_ | 1797031688860073984 |
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| author | , Dante Alighiri , Bambang Purwono , M. Muchalal |
| author_facet | , Dante Alighiri , Bambang Purwono , M. Muchalal |
| author_sort | , Dante Alighiri , Bambang Purwono , M. Muchalal |
| collection | UGM |
| description | <p>Synthesis of 3-(3-allyl-4-hydroxy-5-methoxy phenyl)-1-phenyl prop-2-en-1-one from vanillin and its potentially application to the development of cyanide and fluoride anion sensor has been investigated. This compound has been synthesized via O-allylation reaction of vanillin (1) produced 4-allyloxy-3- methoxy benzaldehyde (2) followed by Claisen-Schmidt condensation reaction between compound 2 with acetophenone gave 3-(4-allyloxy-3-methoxy phenyl)-1-phenyl prop-2-en-1-one (3) in 97.28% yield and Claisen rearrangement of compound 3 produced 3-(3-allyl-4-hydroxy-5-methoxy phenyl)-1-phenyl prop-2- en-1-one (4) in 97.03% yield. Based on color change in the various of anion indicated that compound 4 showed ionochromic phenomenon and its potentially application to the development of anion sensor. The compound 4 could detect cyanide and fluoride anion with limit of detection 200 ppm and 3000 ppm, respectively. Compound 4 could also be used as a material in the preparation of paper indicator for cyanide and fluoride anion.</p> |
| first_indexed | 2024-03-13T22:25:51Z |
| format | Article |
| id | oai:generic.eprints.org:95459 |
| institution | Universiti Gadjah Mada |
| last_indexed | 2024-03-13T22:25:51Z |
| publishDate | 2010 |
| publisher | [Yogyakarta] : Chemistry Departement Universitas Gadjah Mada |
| record_format | dspace |
| spelling | oai:generic.eprints.org:954592014-11-28T07:34:51Z https://repository.ugm.ac.id/95459/ SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR , Dante Alighiri , Bambang Purwono , M. Muchalal <p>Synthesis of 3-(3-allyl-4-hydroxy-5-methoxy phenyl)-1-phenyl prop-2-en-1-one from vanillin and its potentially application to the development of cyanide and fluoride anion sensor has been investigated. This compound has been synthesized via O-allylation reaction of vanillin (1) produced 4-allyloxy-3- methoxy benzaldehyde (2) followed by Claisen-Schmidt condensation reaction between compound 2 with acetophenone gave 3-(4-allyloxy-3-methoxy phenyl)-1-phenyl prop-2-en-1-one (3) in 97.28% yield and Claisen rearrangement of compound 3 produced 3-(3-allyl-4-hydroxy-5-methoxy phenyl)-1-phenyl prop-2- en-1-one (4) in 97.03% yield. Based on color change in the various of anion indicated that compound 4 showed ionochromic phenomenon and its potentially application to the development of anion sensor. The compound 4 could detect cyanide and fluoride anion with limit of detection 200 ppm and 3000 ppm, respectively. Compound 4 could also be used as a material in the preparation of paper indicator for cyanide and fluoride anion.</p> [Yogyakarta] : Chemistry Departement Universitas Gadjah Mada 2010 Article NonPeerReviewed , Dante Alighiri , Bambang Purwono , M. Muchalal (2010) SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR. text. http://repository.ugm.ac.id/digitasi/index.php?module=cari_hasil_full&idbuku=3277 |
| spellingShingle | , Dante Alighiri , Bambang Purwono , M. Muchalal SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR |
| title | SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR |
| title_full | SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR |
| title_fullStr | SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR |
| title_full_unstemmed | SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR |
| title_short | SYNTHESIS OF 3-(3-ALLYL-4-HYDROXY-5-METHOXY PHENYL)-1- PHENYL PROP-2-EN-1-ONE FROM VANILLIN AND ITS POTENTIALLY APPLICATION TO THE DEVELOPMENT OF CYANIDE AND FLUORIDE ANION SENSOR |
| title_sort | synthesis of 3 3 allyl 4 hydroxy 5 methoxy phenyl 1 phenyl prop 2 en 1 one from vanillin and its potentially application to the development of cyanide and fluoride anion sensor |
| work_keys_str_mv | AT dantealighiribambangpurwonommuchalal synthesisof33allyl4hydroxy5methoxyphenyl1phenylprop2en1onefromvanillinanditspotentiallyapplicationtothedevelopmentofcyanideandfluorideanionsensor |