Lanthanide and transition metal complexes of nitrogen and oxygen donor macrocyclic ligands

This thesis is concerned with the synthesis and characterisation of altogether twenty 18- and 24-membered macrocyclic ligands, incorporating the pyridyl and phenolic substituents in the cavity, coupled with their lanthanide and transition metal complexes. Initially a survey of the synthesis and char...

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Bibliographic Details
Main Author: Evagorou, Evagoras George
Format: Thesis
Language:English
Published: 1994
Subjects:
Online Access:https://repository.londonmet.ac.uk/2970/1/240859.pdf
Description
Summary:This thesis is concerned with the synthesis and characterisation of altogether twenty 18- and 24-membered macrocyclic ligands, incorporating the pyridyl and phenolic substituents in the cavity, coupled with their lanthanide and transition metal complexes. Initially a survey of the synthesis and characteristics of related macrocycles is presented. The application of lanthanide metal complexes as contrast agents for magnetic resonance imaging (MRI) is discussed.