Lanthanide and transition metal complexes of nitrogen and oxygen donor macrocyclic ligands
This thesis is concerned with the synthesis and characterisation of altogether twenty 18- and 24-membered macrocyclic ligands, incorporating the pyridyl and phenolic substituents in the cavity, coupled with their lanthanide and transition metal complexes. Initially a survey of the synthesis and char...
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Format: | Thesis |
Language: | English |
Published: |
1994
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Subjects: | |
Online Access: | https://repository.londonmet.ac.uk/2970/1/240859.pdf |
Summary: | This thesis is concerned with the synthesis and characterisation of altogether twenty 18- and 24-membered macrocyclic ligands, incorporating the pyridyl and phenolic substituents in the cavity, coupled with their lanthanide and transition metal complexes. Initially a survey of the synthesis and characteristics of related macrocycles is presented. The application of lanthanide metal complexes as contrast agents for magnetic resonance imaging (MRI) is discussed. |
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