Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline
Hexagonally packed Pd nanoarray catalyst was prepared via the "two solvents" strategy with mesoporous molecular sieve SBA-15 as a hard template. By using S-proline as the chiral modifier, the catalyst exhibited superior activity and selectivity in liquid-phase hydrogenation of acetophenone...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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| _version_ | 1797050270485577728 |
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| author | Chen, X Lou, Z Qiao, M Fan, K Tsang, S He, Y |
| author_facet | Chen, X Lou, Z Qiao, M Fan, K Tsang, S He, Y |
| author_sort | Chen, X |
| collection | OXFORD |
| description | Hexagonally packed Pd nanoarray catalyst was prepared via the "two solvents" strategy with mesoporous molecular sieve SBA-15 as a hard template. By using S-proline as the chiral modifier, the catalyst exhibited superior activity and selectivity in liquid-phase hydrogenation of acetophenone to R-(+)-1-phenylethanol with up to 100% chemoselectivity and 28.8% enantiomeric excess. The presence of S-proline and the regular hexagonal mesostructure of the Pd nanoarray catalyst are crucial for its superior catalytic performance. © 2008 American Chemical Society. |
| first_indexed | 2024-03-06T18:02:42Z |
| format | Journal article |
| id | oxford-uuid:005bc5b8-c175-4122-ab64-74e50b37912c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:02:42Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:005bc5b8-c175-4122-ab64-74e50b37912c2022-03-26T08:29:04ZHexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-prolineJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:005bc5b8-c175-4122-ab64-74e50b37912cEnglishSymplectic Elements at Oxford2008Chen, XLou, ZQiao, MFan, KTsang, SHe, YHexagonally packed Pd nanoarray catalyst was prepared via the "two solvents" strategy with mesoporous molecular sieve SBA-15 as a hard template. By using S-proline as the chiral modifier, the catalyst exhibited superior activity and selectivity in liquid-phase hydrogenation of acetophenone to R-(+)-1-phenylethanol with up to 100% chemoselectivity and 28.8% enantiomeric excess. The presence of S-proline and the regular hexagonal mesostructure of the Pd nanoarray catalyst are crucial for its superior catalytic performance. © 2008 American Chemical Society. |
| spellingShingle | Chen, X Lou, Z Qiao, M Fan, K Tsang, S He, Y Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline |
| title | Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline |
| title_full | Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline |
| title_fullStr | Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline |
| title_full_unstemmed | Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline |
| title_short | Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline |
| title_sort | hexagonally packed pd nanoarray catalyst for liquid phase enantioselective hydrogenation of acetophenone to r 1 phenylethanol in the presence of s proline |
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