A [2]catenane displaying pirouetting motion triggered by debenzylation and locked by chloride anion recognition.

Chloride locks the rings: Debenzylation of a chloride-templated N-benzyl pyridinium catenane, allows for a 180° "pirouetting" of the rings in the resulting neutral pyridyl catenane (see scheme). The catenane may be returned to its original co-conformation by chloride recognition as evidenc...

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Hlavní autoři: Evans, N, Serpell, C, Beer, P
Médium: Journal article
Jazyk:English
Vydáno: 2011