Small molecule activation by frustrated Lewis pairs.
A series of frustrated Lewis pairs (FLPs) based on the Lewis acids tris(perchloroaryl)borane (BAr(Cl)), and tris(2,2',2''-perfluorobiphenyl)borane (PBB) and trialkylphosphines were prepared; their ability to effect the heterolytic cleavage of dihydrogen, insert carbon dioxide into the...
| Príomhchruthaitheoirí: | , , , , , |
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| Formáid: | Journal article |
| Teanga: | English |
| Foilsithe / Cruthaithe: |
2013
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| Achoimre: | A series of frustrated Lewis pairs (FLPs) based on the Lewis acids tris(perchloroaryl)borane (BAr(Cl)), and tris(2,2',2''-perfluorobiphenyl)borane (PBB) and trialkylphosphines were prepared; their ability to effect the heterolytic cleavage of dihydrogen, insert carbon dioxide into the borohydride, and reduce the resulting formatoborate to methanol were studied. Additionally, the insertion of CO(2) into a B-OH bond is explored with the ultimate aim of developing a homogeneous, catalytic preparation of carbonates. The compound [PBB-OH][H-P((t)Bu)(3)] was characterised by single crystal X-ray crystallography. |
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