Time-resolved dissociation of the H-2-OH entrance channel complex

Time-resolved dissociation of the H-2-OH entrance channel complex

Time-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product stat...

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Bibliographic Details
Main Authors: Krause, P, Clary, D, Anderson, D, Todd, M, Schwartz, R, Lester, M
Format: Journal article
Language:English
Published: 1998
Description
Summary:Time-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product state distributions for D2-OH. The excited vibrational state lifetimes are 10-9 and 10-6 s for the complexes containing D2 and H2, respectively.

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