Time-resolved dissociation of the H-2-OH entrance channel complex

Time-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product stat...

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Main Authors: Krause, P, Clary, D, Anderson, D, Todd, M, Schwartz, R, Lester, M
Format: Journal article
Language:English
Published: 1998
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author Krause, P
Clary, D
Anderson, D
Todd, M
Schwartz, R
Lester, M
author_facet Krause, P
Clary, D
Anderson, D
Todd, M
Schwartz, R
Lester, M
author_sort Krause, P
collection OXFORD
description Time-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product state distributions for D2-OH. The excited vibrational state lifetimes are 10-9 and 10-6 s for the complexes containing D2 and H2, respectively.
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spelling oxford-uuid:01851c43-44b7-476f-8891-14d40ba56f332022-03-26T08:35:32ZTime-resolved dissociation of the H-2-OH entrance channel complexJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:01851c43-44b7-476f-8891-14d40ba56f33EnglishSymplectic Elements at Oxford1998Krause, PClary, DAnderson, DTodd, MSchwartz, RLester, MTime-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product state distributions for D2-OH. The excited vibrational state lifetimes are 10-9 and 10-6 s for the complexes containing D2 and H2, respectively.
spellingShingle Krause, P
Clary, D
Anderson, D
Todd, M
Schwartz, R
Lester, M
Time-resolved dissociation of the H-2-OH entrance channel complex
title Time-resolved dissociation of the H-2-OH entrance channel complex
title_full Time-resolved dissociation of the H-2-OH entrance channel complex
title_fullStr Time-resolved dissociation of the H-2-OH entrance channel complex
title_full_unstemmed Time-resolved dissociation of the H-2-OH entrance channel complex
title_short Time-resolved dissociation of the H-2-OH entrance channel complex
title_sort time resolved dissociation of the h 2 oh entrance channel complex
work_keys_str_mv AT krausep timeresolveddissociationoftheh2ohentrancechannelcomplex
AT claryd timeresolveddissociationoftheh2ohentrancechannelcomplex
AT andersond timeresolveddissociationoftheh2ohentrancechannelcomplex
AT toddm timeresolveddissociationoftheh2ohentrancechannelcomplex
AT schwartzr timeresolveddissociationoftheh2ohentrancechannelcomplex
AT lesterm timeresolveddissociationoftheh2ohentrancechannelcomplex