Time-resolved dissociation of the H-2-OH entrance channel complex
Time-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product stat...
Main Authors: | , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
1998
|
_version_ | 1797050513511940096 |
---|---|
author | Krause, P Clary, D Anderson, D Todd, M Schwartz, R Lester, M |
author_facet | Krause, P Clary, D Anderson, D Todd, M Schwartz, R Lester, M |
author_sort | Krause, P |
collection | OXFORD |
description | Time-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product state distributions for D2-OH. The excited vibrational state lifetimes are 10-9 and 10-6 s for the complexes containing D2 and H2, respectively. |
first_indexed | 2024-03-06T18:06:17Z |
format | Journal article |
id | oxford-uuid:01851c43-44b7-476f-8891-14d40ba56f33 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T18:06:17Z |
publishDate | 1998 |
record_format | dspace |
spelling | oxford-uuid:01851c43-44b7-476f-8891-14d40ba56f332022-03-26T08:35:32ZTime-resolved dissociation of the H-2-OH entrance channel complexJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:01851c43-44b7-476f-8891-14d40ba56f33EnglishSymplectic Elements at Oxford1998Krause, PClary, DAnderson, DTodd, MSchwartz, RLester, MTime-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product state distributions for D2-OH. The excited vibrational state lifetimes are 10-9 and 10-6 s for the complexes containing D2 and H2, respectively. |
spellingShingle | Krause, P Clary, D Anderson, D Todd, M Schwartz, R Lester, M Time-resolved dissociation of the H-2-OH entrance channel complex |
title | Time-resolved dissociation of the H-2-OH entrance channel complex |
title_full | Time-resolved dissociation of the H-2-OH entrance channel complex |
title_fullStr | Time-resolved dissociation of the H-2-OH entrance channel complex |
title_full_unstemmed | Time-resolved dissociation of the H-2-OH entrance channel complex |
title_short | Time-resolved dissociation of the H-2-OH entrance channel complex |
title_sort | time resolved dissociation of the h 2 oh entrance channel complex |
work_keys_str_mv | AT krausep timeresolveddissociationoftheh2ohentrancechannelcomplex AT claryd timeresolveddissociationoftheh2ohentrancechannelcomplex AT andersond timeresolveddissociationoftheh2ohentrancechannelcomplex AT toddm timeresolveddissociationoftheh2ohentrancechannelcomplex AT schwartzr timeresolveddissociationoftheh2ohentrancechannelcomplex AT lesterm timeresolveddissociationoftheh2ohentrancechannelcomplex |