Synthesis, characterization and reactivity of complex tricyclic oxonium ions, proposed intermediates in natural product biosynthesis

Reactive intermediates frequently play significant roles in the biosynthesis of numerous classes of natural products although the direct observation of these biosynthetically relevant species is rare. We present here direct evidence for the existence of complex, thermally unstable, tricyclic oxonium...

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Detalhes bibliográficos
Principais autores: Chan, HSS, Nguyen, QNN, Paton, RS, Burton, JW
Formato: Journal article
Idioma:English
Publicado em: American Chemical Society 2019