Shape-shifting polyhedral droplets
Cooled oil emulsion droplets in aqueous surfactant solution have been observed to flatten into a remarkable host of polygonal shapes with straight edges and sharp corners, but different driving mechanisms—(i) a partial phase transition of the liquid bulk oil into a plastic rotator phase near the dro...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Physical Society
2019
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| _version_ | 1797050559649284096 |
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| author | Haas, PA Cholakova, D Denkov, N Goldstein, RE Smoukov, SK |
| author_facet | Haas, PA Cholakova, D Denkov, N Goldstein, RE Smoukov, SK |
| author_sort | Haas, PA |
| collection | OXFORD |
| description | Cooled oil emulsion droplets in aqueous surfactant solution have been observed to flatten into a remarkable host of polygonal shapes with straight edges and sharp corners, but different driving mechanisms—(i) a partial phase transition of the liquid bulk oil into a plastic rotator phase near the droplet interface and (ii) buckling of the interfacially frozen surfactant monolayer enabled by a drastic lowering of surface tension—have been proposed. Here, combining experiment and theory, we analyze the initial stages of the evolution of these “shape-shifting” droplets, during which a polyhedral droplet flattens into a polygonal platelet under cooling and gravity. Using reflected-light microscopy, we reveal how icosahedral droplets evolve through an intermediate octahedral stage to flatten into hexagonal platelets. This behavior is reproduced by a theoretical model of the phase transition mechanism, but the buckling mechanism can only reproduce the flattening if the deformations are driven by buoyancy. This requires surface tension to decrease by several orders of magnitude during cooling and yields bending modulus estimates orders of magnitude below experimental values. The analysis thus shows that the phase transition mechanism underlies the observed “shape-shifting” phenomena. |
| first_indexed | 2024-03-06T18:06:57Z |
| format | Journal article |
| id | oxford-uuid:01bd46f7-8f2b-416a-9bff-2c5ba7f34e78 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:06:57Z |
| publishDate | 2019 |
| publisher | American Physical Society |
| record_format | dspace |
| spelling | oxford-uuid:01bd46f7-8f2b-416a-9bff-2c5ba7f34e782022-03-26T08:36:43ZShape-shifting polyhedral dropletsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:01bd46f7-8f2b-416a-9bff-2c5ba7f34e78EnglishSymplectic ElementsAmerican Physical Society2019Haas, PACholakova, DDenkov, NGoldstein, RESmoukov, SKCooled oil emulsion droplets in aqueous surfactant solution have been observed to flatten into a remarkable host of polygonal shapes with straight edges and sharp corners, but different driving mechanisms—(i) a partial phase transition of the liquid bulk oil into a plastic rotator phase near the droplet interface and (ii) buckling of the interfacially frozen surfactant monolayer enabled by a drastic lowering of surface tension—have been proposed. Here, combining experiment and theory, we analyze the initial stages of the evolution of these “shape-shifting” droplets, during which a polyhedral droplet flattens into a polygonal platelet under cooling and gravity. Using reflected-light microscopy, we reveal how icosahedral droplets evolve through an intermediate octahedral stage to flatten into hexagonal platelets. This behavior is reproduced by a theoretical model of the phase transition mechanism, but the buckling mechanism can only reproduce the flattening if the deformations are driven by buoyancy. This requires surface tension to decrease by several orders of magnitude during cooling and yields bending modulus estimates orders of magnitude below experimental values. The analysis thus shows that the phase transition mechanism underlies the observed “shape-shifting” phenomena. |
| spellingShingle | Haas, PA Cholakova, D Denkov, N Goldstein, RE Smoukov, SK Shape-shifting polyhedral droplets |
| title | Shape-shifting polyhedral droplets |
| title_full | Shape-shifting polyhedral droplets |
| title_fullStr | Shape-shifting polyhedral droplets |
| title_full_unstemmed | Shape-shifting polyhedral droplets |
| title_short | Shape-shifting polyhedral droplets |
| title_sort | shape shifting polyhedral droplets |
| work_keys_str_mv | AT haaspa shapeshiftingpolyhedraldroplets AT cholakovad shapeshiftingpolyhedraldroplets AT denkovn shapeshiftingpolyhedraldroplets AT goldsteinre shapeshiftingpolyhedraldroplets AT smoukovsk shapeshiftingpolyhedraldroplets |