Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C-H Activation

Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C-H Activation

Cationic Ir(III) systems supported by a bis(expanded NHC) framework and featuring both agostic C-H and cis alkyl/hydride ligand sets have been targeted by protonation of the corresponding bis(alkyl) hydride complexes. Remarkably, the steric shielding afforded by the NHC substituents is such that the...

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Dettagli Bibliografici
Autori principali:	Phillips, N, Rowles, J, Kelly, M, Riddlestone, I, Rees, N, Dervisi, A, Fallis, I, Aldridge, S
Natura:	Journal article
Lingua:	English
Pubblicazione:	2012

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