Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C-H Activation
Cationic Ir(III) systems supported by a bis(expanded NHC) framework and featuring both agostic C-H and cis alkyl/hydride ligand sets have been targeted by protonation of the corresponding bis(alkyl) hydride complexes. Remarkably, the steric shielding afforded by the NHC substituents is such that the...
| मुख्य लेखकों: | , , , , , , , |
|---|---|
| स्वरूप: | Journal article |
| भाषा: | English |
| प्रकाशित: |
2012
|