A porphyrin fused to four anthracenes.
We have synthesized a fused tetraanthracenylporphyrin by oxidation of a meso-anthracenyl nickel(II) porphyrin with FeCl(3). This compound exhibits an intense red-shifted absorption spectrum (λ(max) = 1417 nm; ε = 1.2 × 10(5) M(-1) cm(-1)) and a small electrochemical HOMO-LUMO gap (0.61 eV). The crys...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2011
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| _version_ | 1826256896618659840 |
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| author | Davis, N Thompson, A Anderson, H |
| author_facet | Davis, N Thompson, A Anderson, H |
| author_sort | Davis, N |
| collection | OXFORD |
| description | We have synthesized a fused tetraanthracenylporphyrin by oxidation of a meso-anthracenyl nickel(II) porphyrin with FeCl(3). This compound exhibits an intense red-shifted absorption spectrum (λ(max) = 1417 nm; ε = 1.2 × 10(5) M(-1) cm(-1)) and a small electrochemical HOMO-LUMO gap (0.61 eV). The crystal structure shows that it forms π-stacked dimers with a short Ni···Ni distance (3.32 Å). |
| first_indexed | 2024-03-06T18:09:33Z |
| format | Journal article |
| id | oxford-uuid:028ae4c8-ff30-42fb-a0c3-00906a91cbb9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:09:33Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:028ae4c8-ff30-42fb-a0c3-00906a91cbb92022-03-26T08:41:17ZA porphyrin fused to four anthracenes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:028ae4c8-ff30-42fb-a0c3-00906a91cbb9EnglishSymplectic Elements at Oxford2011Davis, NThompson, AAnderson, HWe have synthesized a fused tetraanthracenylporphyrin by oxidation of a meso-anthracenyl nickel(II) porphyrin with FeCl(3). This compound exhibits an intense red-shifted absorption spectrum (λ(max) = 1417 nm; ε = 1.2 × 10(5) M(-1) cm(-1)) and a small electrochemical HOMO-LUMO gap (0.61 eV). The crystal structure shows that it forms π-stacked dimers with a short Ni···Ni distance (3.32 Å). |
| spellingShingle | Davis, N Thompson, A Anderson, H A porphyrin fused to four anthracenes. |
| title | A porphyrin fused to four anthracenes. |
| title_full | A porphyrin fused to four anthracenes. |
| title_fullStr | A porphyrin fused to four anthracenes. |
| title_full_unstemmed | A porphyrin fused to four anthracenes. |
| title_short | A porphyrin fused to four anthracenes. |
| title_sort | porphyrin fused to four anthracenes |
| work_keys_str_mv | AT davisn aporphyrinfusedtofouranthracenes AT thompsona aporphyrinfusedtofouranthracenes AT andersonh aporphyrinfusedtofouranthracenes AT davisn porphyrinfusedtofouranthracenes AT thompsona porphyrinfusedtofouranthracenes AT andersonh porphyrinfusedtofouranthracenes |