Synthetic, structural and reaction chemistry of N-heterocyclic germylene and stannylene compounds featuring N-boryl substituents
This study details the syntheses of N-heterocyclic germylenes and stannylenes featuring diazaborolyl groups, {(HCDippN)2B} (Dipp = 2,6-iPr2C6H3), as both of the N-bound substituents, with a view to generating electron rich and sterically protected metal centres. The energies of their key frontier or...
المؤلفون الرئيسيون: | Kristinsdóttir, L, Oldroyd, N, Grabiner, R, Knights, A, Heilmann, A, Protchenko, A, Niu, H, Kolychev, E, Campos, J, Hicks, J, Christensen, K, Aldridge, S |
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التنسيق: | Journal article |
اللغة: | English |
منشور في: |
Royal Society of Chemistry
2019
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مواد مشابهة
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Enabling and probing oxidative addition and reductive elimination at a group 14 metal center: cleavage and functionalization of E-H bonds by a bis(boryl)stannylene
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