A new conducting ternary nitride: NaxTa3N5 (0<=x<=1.4)

A new conducting ternary nitride: NaxTa3N5 (0<=x<=1.4)

Topotactic insertion of sodium into the channel structure of Ta3N5has been accomplished by the reaction between Na and Ta3N5at temperatures between 450 and 600°C in sealed Ni tubes. The limiting stoichiometry of NaxTa3N5obtained isx≈1.4. The structure of Na1.0Ta3N5has been refined using Rietveld ful...

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Bibliographic Details
Main Authors:	Clarke, S, DiSalvo, F
Format:	Journal article
Language:	English
Published:	1997

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