Control of the exo and endo pathways of the Diels-Alder reaction by antibody catalysis.
Catalytic antibodies that control the reaction pathways of the Diels-Alder cycloaddition have been generated. One antibody catalyzes the favored endo and the other the disfavored exo pathway to yield the respective cis and trans adducts in enantiomerically pure form. A comparison of the x-ray struct...
主要な著者: | Gouverneur, V, Houk, K, de Pascual-Teresa, B, Beno, B, Janda, K, Lerner, R |
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フォーマット: | Journal article |
言語: | English |
出版事項: |
1993
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