HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS
The new complexes [M(η5-C5H4CH2O)2Mo(NO)L{black star}]; M = Fe or Ru and L{black star} = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene ligand, have been prepared and characterised along with the related trimetallic complex [{Fe(η5-C5H5)(η5-C5H4CH2O)}2Mo(NO)L{black s...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1987
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| _version_ | 1826257080631164928 |
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| author | Beer, P Jones, C Mccleverty, J Sidebotham, R |
| author_facet | Beer, P Jones, C Mccleverty, J Sidebotham, R |
| author_sort | Beer, P |
| collection | OXFORD |
| description | The new complexes [M(η5-C5H4CH2O)2Mo(NO)L{black star}]; M = Fe or Ru and L{black star} = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene ligand, have been prepared and characterised along with the related trimetallic complex [{Fe(η5-C5H5)(η5-C5H4CH2O)}2Mo(NO)L{black star}]. Their electrochemical properties are reported, and the reduction potentials for the {Mo(NO)}4+ redox centre in the chelated species are 100 mV more anodic than for that in the trimetallic non-chelated complex. © 1987. |
| first_indexed | 2024-03-06T18:12:27Z |
| format | Journal article |
| id | oxford-uuid:037d84ba-55a9-4a54-a559-f905044ff88a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:12:27Z |
| publishDate | 1987 |
| record_format | dspace |
| spelling | oxford-uuid:037d84ba-55a9-4a54-a559-f905044ff88a2022-03-26T08:46:28ZHETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:037d84ba-55a9-4a54-a559-f905044ff88aEnglishSymplectic Elements at Oxford1987Beer, PJones, CMccleverty, JSidebotham, RThe new complexes [M(η5-C5H4CH2O)2Mo(NO)L{black star}]; M = Fe or Ru and L{black star} = (hydro)tris(3,5-dimethylpyrazolyl)borate, which contain a chelating metallocene ligand, have been prepared and characterised along with the related trimetallic complex [{Fe(η5-C5H5)(η5-C5H4CH2O)}2Mo(NO)L{black star}]. Their electrochemical properties are reported, and the reduction potentials for the {Mo(NO)}4+ redox centre in the chelated species are 100 mV more anodic than for that in the trimetallic non-chelated complex. © 1987. |
| spellingShingle | Beer, P Jones, C Mccleverty, J Sidebotham, R HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS |
| title | HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS |
| title_full | HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS |
| title_fullStr | HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS |
| title_full_unstemmed | HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS |
| title_short | HETERO-BI-METALLIC AND TRI-METALLIC COMPLEXES CONTAINING BOTH ELECTRON RELEASING AND ELECTRON ACCEPTING REDOX CENTERS |
| title_sort | hetero bi metallic and tri metallic complexes containing both electron releasing and electron accepting redox centers |
| work_keys_str_mv | AT beerp heterobimetallicandtrimetalliccomplexescontainingbothelectronreleasingandelectronacceptingredoxcenters AT jonesc heterobimetallicandtrimetalliccomplexescontainingbothelectronreleasingandelectronacceptingredoxcenters AT mcclevertyj heterobimetallicandtrimetalliccomplexescontainingbothelectronreleasingandelectronacceptingredoxcenters AT sidebothamr heterobimetallicandtrimetalliccomplexescontainingbothelectronreleasingandelectronacceptingredoxcenters |