Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission

Rates of vibrational quenching of NO (v = 1-16) in collisions with O2 have been measured at 295 K. NO(v) was formed both by the O(1D) + N2O reaction and the 193 nm photolysis of NO2, and time resolved FT-IR emission was used to follow the behaviour of the vibrationally excited species. Rate constant...

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Main Authors: Hancock, G, Morrison, M, Saunders, M
Format: Journal article
Language:English
Published: 2006
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author Hancock, G
Morrison, M
Saunders, M
author_facet Hancock, G
Morrison, M
Saunders, M
author_sort Hancock, G
collection OXFORD
description Rates of vibrational quenching of NO (v = 1-16) in collisions with O2 have been measured at 295 K. NO(v) was formed both by the O(1D) + N2O reaction and the 193 nm photolysis of NO2, and time resolved FT-IR emission was used to follow the behaviour of the vibrationally excited species. Rate constants were found to peak close to resonance for the single quantum exchange process between NO and O2. © 2006 Elsevier B.V. All rights reserved.
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spelling oxford-uuid:0382ddb5-b7aa-47d0-97ff-e4633679dd582022-03-26T08:46:48ZVibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emissionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0382ddb5-b7aa-47d0-97ff-e4633679dd58EnglishSymplectic Elements at Oxford2006Hancock, GMorrison, MSaunders, MRates of vibrational quenching of NO (v = 1-16) in collisions with O2 have been measured at 295 K. NO(v) was formed both by the O(1D) + N2O reaction and the 193 nm photolysis of NO2, and time resolved FT-IR emission was used to follow the behaviour of the vibrationally excited species. Rate constants were found to peak close to resonance for the single quantum exchange process between NO and O2. © 2006 Elsevier B.V. All rights reserved.
spellingShingle Hancock, G
Morrison, M
Saunders, M
Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission
title Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission
title_full Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission
title_fullStr Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission
title_full_unstemmed Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission
title_short Vibrational relaxation of NO (v=1-16) in collisions with O-2 studied by time resolved Fourier transform infrared emission
title_sort vibrational relaxation of no v 1 16 in collisions with o 2 studied by time resolved fourier transform infrared emission
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AT morrisonm vibrationalrelaxationofnov116incollisionswitho2studiedbytimeresolvedfouriertransforminfraredemission
AT saundersm vibrationalrelaxationofnov116incollisionswitho2studiedbytimeresolvedfouriertransforminfraredemission