A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions.
Salt metathesis reactions between ethylenediamine (en) solutions of the K(3)E(7) (E = P, As) Zintl phases and post-transition metal halides (InCl(3), TlCl, SnI(2) and PbI(2)) have yielded a family of novel heteroatomic cluster anions, [In(E(7))(2)](3-), [TlE(7)](2-) and [E'E(15)](3-) (E' =...
| Main Authors: | , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2011
|
| _version_ | 1797051148161515520 |
|---|---|
| author | Knapp, C Large, J Rees, N Goicoechea, J |
| author_facet | Knapp, C Large, J Rees, N Goicoechea, J |
| author_sort | Knapp, C |
| collection | OXFORD |
| description | Salt metathesis reactions between ethylenediamine (en) solutions of the K(3)E(7) (E = P, As) Zintl phases and post-transition metal halides (InCl(3), TlCl, SnI(2) and PbI(2)) have yielded a family of novel heteroatomic cluster anions, [In(E(7))(2)](3-), [TlE(7)](2-) and [E'E(15)](3-) (E' = Sn, Pb; E = P, As). Several of these new species have been characterized by single-crystal X-ray diffraction as salts of sequestered potassium cations in [K(2,2,2-crypt)](3)[In(P(7))(2)]·3.5py (1), [K(2,2,2-crypt)](2)[TlP(7)]·py (3), [K(18-crown-6)](2)[TlAs(7)] (4b), [K(2,2,2-crypt)](3)[E'P(15)]·en (E' = Sn (5), Pb (6)) and [K(2,2,2-crypt)](3)[SnAs(15)]·2en (7). The presence of all of the cluster anions in solution was confirmed by electrospray mass-spectrometry and by (1)H and (31)P{(1)H} NMR spectroscopy when pertinent. |
| first_indexed | 2024-03-06T18:15:47Z |
| format | Journal article |
| id | oxford-uuid:0490c511-122b-42fd-91e8-df62c407a520 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:15:47Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:0490c511-122b-42fd-91e8-df62c407a5202022-03-26T08:52:31ZA versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0490c511-122b-42fd-91e8-df62c407a520EnglishSymplectic Elements at Oxford2011Knapp, CLarge, JRees, NGoicoechea, JSalt metathesis reactions between ethylenediamine (en) solutions of the K(3)E(7) (E = P, As) Zintl phases and post-transition metal halides (InCl(3), TlCl, SnI(2) and PbI(2)) have yielded a family of novel heteroatomic cluster anions, [In(E(7))(2)](3-), [TlE(7)](2-) and [E'E(15)](3-) (E' = Sn, Pb; E = P, As). Several of these new species have been characterized by single-crystal X-ray diffraction as salts of sequestered potassium cations in [K(2,2,2-crypt)](3)[In(P(7))(2)]·3.5py (1), [K(2,2,2-crypt)](2)[TlP(7)]·py (3), [K(18-crown-6)](2)[TlAs(7)] (4b), [K(2,2,2-crypt)](3)[E'P(15)]·en (E' = Sn (5), Pb (6)) and [K(2,2,2-crypt)](3)[SnAs(15)]·2en (7). The presence of all of the cluster anions in solution was confirmed by electrospray mass-spectrometry and by (1)H and (31)P{(1)H} NMR spectroscopy when pertinent. |
| spellingShingle | Knapp, C Large, J Rees, N Goicoechea, J A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions. |
| title | A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions. |
| title_full | A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions. |
| title_fullStr | A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions. |
| title_full_unstemmed | A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions. |
| title_short | A versatile salt-metathesis route to heteroatomic clusters derived from phosphorus and arsenic Zintl anions. |
| title_sort | versatile salt metathesis route to heteroatomic clusters derived from phosphorus and arsenic zintl anions |
| work_keys_str_mv | AT knappc aversatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions AT largej aversatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions AT reesn aversatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions AT goicoecheaj aversatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions AT knappc versatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions AT largej versatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions AT reesn versatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions AT goicoecheaj versatilesaltmetathesisroutetoheteroatomicclustersderivedfromphosphorusandarseniczintlanions |