La2SrCr2O7F2: A Ruddlesden-Popper oxyfluoride containing octahedrally coordinated Cr(4+) centers

The low-temperature fluorination of the n = 2 Ruddlesden-Popper phase La2SrCr2O7 yields La2SrCr2O7F2 via a topochemical fluorine insertion reaction. The structure-conserving nature of the fluorination reaction means that the chromium centers of the initial oxide phase retain an octahedral coordinati...

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Bibliographic Details
Main Authors: Zhang, R, Read, G, Lang, F, Lancaster, T, Blundell, S, Hayward, M
Format: Journal article
Language:English
Published: American Chemical Society 2016