Rate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode Voltammetry

A simple method is introduced which enables the simultaneous determination of both the maximum CO2 concentration and kinetics of CO2 uptake and release by a room temperature ionic liquid. This method is based upon the analysis of chronoamperometry recorded in bulk ionic liquid at intervals during ex...

Full description

Bibliographic Details
Main Authors: Li, P, Henstridge, M, Xiong, L, Compton, R
Format: Journal article
Language:English
Published: 2013
_version_ 1826257341216980992
author Li, P
Henstridge, M
Xiong, L
Compton, R
author_facet Li, P
Henstridge, M
Xiong, L
Compton, R
author_sort Li, P
collection OXFORD
description A simple method is introduced which enables the simultaneous determination of both the maximum CO2 concentration and kinetics of CO2 uptake and release by a room temperature ionic liquid. This method is based upon the analysis of chronoamperometry recorded in bulk ionic liquid at intervals during exposure to CO2 and subsequent exposure to vacuum to remove the dissolved CO2. Comparing experimental data with a numerical model reveals the rate-limiting factors for both uptake and release of CO2. © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
first_indexed 2024-03-06T18:16:39Z
format Journal article
id oxford-uuid:04d8123c-5f9f-4667-b25b-a458c3028941
institution University of Oxford
language English
last_indexed 2024-03-06T18:16:39Z
publishDate 2013
record_format dspace
spelling oxford-uuid:04d8123c-5f9f-4667-b25b-a458c30289412022-03-26T08:53:53ZRate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode VoltammetryJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:04d8123c-5f9f-4667-b25b-a458c3028941EnglishSymplectic Elements at Oxford2013Li, PHenstridge, MXiong, LCompton, RA simple method is introduced which enables the simultaneous determination of both the maximum CO2 concentration and kinetics of CO2 uptake and release by a room temperature ionic liquid. This method is based upon the analysis of chronoamperometry recorded in bulk ionic liquid at intervals during exposure to CO2 and subsequent exposure to vacuum to remove the dissolved CO2. Comparing experimental data with a numerical model reveals the rate-limiting factors for both uptake and release of CO2. © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
spellingShingle Li, P
Henstridge, M
Xiong, L
Compton, R
Rate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode Voltammetry
title Rate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode Voltammetry
title_full Rate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode Voltammetry
title_fullStr Rate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode Voltammetry
title_full_unstemmed Rate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode Voltammetry
title_short Rate and Extent of Carbon Dioxide Uptake In Room Temperature Ionic Liquids: A New Approach Using Microdisc Electrode Voltammetry
title_sort rate and extent of carbon dioxide uptake in room temperature ionic liquids a new approach using microdisc electrode voltammetry
work_keys_str_mv AT lip rateandextentofcarbondioxideuptakeinroomtemperatureionicliquidsanewapproachusingmicrodiscelectrodevoltammetry
AT henstridgem rateandextentofcarbondioxideuptakeinroomtemperatureionicliquidsanewapproachusingmicrodiscelectrodevoltammetry
AT xiongl rateandextentofcarbondioxideuptakeinroomtemperatureionicliquidsanewapproachusingmicrodiscelectrodevoltammetry
AT comptonr rateandextentofcarbondioxideuptakeinroomtemperatureionicliquidsanewapproachusingmicrodiscelectrodevoltammetry