Control of electron transfer in a conjugated porphyrin dimer by selective excitation of planar and perpendicular conformers.
A donor-acceptor system is presented in which the electron-transfer rates can be sensitively controlled by means of excitation wavelength and temperature. The electron donor is a butadiyne-linked zinc porphyrin dimer that is connected to a C(60) electron acceptor. The broad distribution of conformat...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2007
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