Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.
(Chemical Equation Presented) Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)] +[BArF4]- (1, Cy = cyclohexyl, ArF = 3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO-2) indicate delocalized π bond...
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| Main Authors: |
Aldridge, S,
Jones, C,
Gans-Eichler, T,
Stasch, A,
Kays, D,
Coombs, N,
Willock, D |
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| 格式: | Journal article
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| 語言: | English |
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| 出版: |
2006
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