Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.
(Chemical Equation Presented) Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)] +[BArF4]- (1, Cy = cyclohexyl, ArF = 3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO-2) indicate delocalized π bond...
Celý popis
Podrobná bibliografie
| Hlavní autoři: |
Aldridge, S,
Jones, C,
Gans-Eichler, T,
Stasch, A,
Kays, D,
Coombs, N,
Willock, D |
|---|
| Médium: | Journal article
|
|---|
| Jazyk: | English |
|---|
| Vydáno: |
2006
|
|---|