Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.
(Chemical Equation Presented) Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)] +[BArF4]- (1, Cy = cyclohexyl, ArF = 3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO-2) indicate delocalized π bond...
| Autores principales: | , , , , , , |
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| Formato: | Journal article |
| Lenguaje: | English |
| Publicado: |
2006
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| _version_ | 1826257378195013632 |
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| author | Aldridge, S Jones, C Gans-Eichler, T Stasch, A Kays, D Coombs, N Willock, D |
| author_facet | Aldridge, S Jones, C Gans-Eichler, T Stasch, A Kays, D Coombs, N Willock, D |
| author_sort | Aldridge, S |
| collection | OXFORD |
| description | (Chemical Equation Presented) Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)] +[BArF4]- (1, Cy = cyclohexyl, ArF = 3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO-2) indicate delocalized π bonding along the linear Fe-B-N framework and significant Fe-B and B-N multiple-bond character. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-06T18:17:15Z |
| format | Journal article |
| id | oxford-uuid:0508e3cb-71cc-4d50-9c20-f3d01a816108 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:17:15Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:0508e3cb-71cc-4d50-9c20-f3d01a8161082022-03-26T08:54:59ZCationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0508e3cb-71cc-4d50-9c20-f3d01a816108EnglishSymplectic Elements at Oxford2006Aldridge, SJones, CGans-Eichler, TStasch, AKays, DCoombs, NWillock, D(Chemical Equation Presented) Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)] +[BArF4]- (1, Cy = cyclohexyl, ArF = 3,5-(CF3)2C6H3; Fe orange, B green, N blue, O red, C gray) was structurally characterized. DFT studies (see HOMO-2) indicate delocalized π bonding along the linear Fe-B-N framework and significant Fe-B and B-N multiple-bond character. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Aldridge, S Jones, C Gans-Eichler, T Stasch, A Kays, D Coombs, N Willock, D Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue. |
| title | Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue. |
| title_full | Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue. |
| title_fullStr | Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue. |
| title_full_unstemmed | Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue. |
| title_short | Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue. |
| title_sort | cationic terminal borylene complexes structure bonding analysis and 4 1 cycloaddition reactivity of a bn vinylidene analogue |
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