NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY
We report the 23Na NMR spectrum of the sodium anion, Na-, in fluid solutions of sodium in N,N-diethylacetamide (DEA); even in the presence of the (amide) carbonyl moiety, the sodide ion exists in this solvent as a stable, gaslike centrosymmetric species with two valence electrons residing in an unpe...
| Main Authors: | , , , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado em: |
1983
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| _version_ | 1826257447132594176 |
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| author | Edwards, P Guy, S Holton, D Johnson, D Slenko, M Mcfarlane, W Wood, B |
| author_facet | Edwards, P Guy, S Holton, D Johnson, D Slenko, M Mcfarlane, W Wood, B |
| author_sort | Edwards, P |
| collection | OXFORD |
| description | We report the 23Na NMR spectrum of the sodium anion, Na-, in fluid solutions of sodium in N,N-diethylacetamide (DEA); even in the presence of the (amide) carbonyl moiety, the sodide ion exists in this solvent as a stable, gaslike centrosymmetric species with two valence electrons residing in an unperturbed 3s orbital on sodium. Proton (1H) and carbon-13 (13C) NMR spectra are consistent with this picture, with solvent nuclei showing only minor shifts from the pure DEA situation. © 1983 American Chemical Society. |
| first_indexed | 2024-03-06T18:18:20Z |
| format | Journal article |
| id | oxford-uuid:0569f7ed-f65b-4f8c-a9f9-9d9ca85eb2cf |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:18:20Z |
| publishDate | 1983 |
| record_format | dspace |
| spelling | oxford-uuid:0569f7ed-f65b-4f8c-a9f9-9d9ca85eb2cf2022-03-26T08:57:04ZNUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETYJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0569f7ed-f65b-4f8c-a9f9-9d9ca85eb2cfEnglishSymplectic Elements at Oxford1983Edwards, PGuy, SHolton, DJohnson, DSlenko, MMcfarlane, WWood, BWe report the 23Na NMR spectrum of the sodium anion, Na-, in fluid solutions of sodium in N,N-diethylacetamide (DEA); even in the presence of the (amide) carbonyl moiety, the sodide ion exists in this solvent as a stable, gaslike centrosymmetric species with two valence electrons residing in an unperturbed 3s orbital on sodium. Proton (1H) and carbon-13 (13C) NMR spectra are consistent with this picture, with solvent nuclei showing only minor shifts from the pure DEA situation. © 1983 American Chemical Society. |
| spellingShingle | Edwards, P Guy, S Holton, D Johnson, D Slenko, M Mcfarlane, W Wood, B NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY |
| title | NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY |
| title_full | NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY |
| title_fullStr | NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY |
| title_full_unstemmed | NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY |
| title_short | NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY |
| title_sort | nuclear magnetic resonance spectrum of the sodium anion in sodium n n diethylacetamide solutions the sodide ion in the presence of a carbonyl moiety |
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