NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE SODIUM ANION IN SODIUM-N,N-DIETHYLACETAMIDE SOLUTIONS - THE SODIDE ION IN THE PRESENCE OF A CARBONYL MOIETY

We report the 23Na NMR spectrum of the sodium anion, Na-, in fluid solutions of sodium in N,N-diethylacetamide (DEA); even in the presence of the (amide) carbonyl moiety, the sodide ion exists in this solvent as a stable, gaslike centrosymmetric species with two valence electrons residing in an unpe...

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Hlavní autoři: Edwards, P, Guy, S, Holton, D, Johnson, D, Slenko, M, Mcfarlane, W, Wood, B
Médium: Journal article
Jazyk:English
Vydáno: 1983