Thinning and opening of carbon nanotubes by oxidation using carbon dioxide
The discovery1 and bulk synthesis2 of carbon nanotubes has stimulated great interest. It has been suggested that these structures may have useful electronic3-5 and mechanical6 properties, and these might be modified by introducing foreign materials into the nanotubes. But the tubes are invariably ca...
| Príomhchruthaitheoirí: | , , |
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| Formáid: | Journal article |
| Teanga: | English |
| Foilsithe / Cruthaithe: |
1993
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| _version_ | 1826257470971969536 |
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| author | Tsang, S Harris, P Green, M |
| author_facet | Tsang, S Harris, P Green, M |
| author_sort | Tsang, S |
| collection | OXFORD |
| description | The discovery1 and bulk synthesis2 of carbon nanotubes has stimulated great interest. It has been suggested that these structures may have useful electronic3-5 and mechanical6 properties, and these might be modified by introducing foreign materials into the nanotubes. But the tubes are invariably capped at the ends. Ajayan and Iijima7 have succeeded in drawing molten material (lead or one of its compounds) into the tubes by heating them in the presence of lead and oxygen; less than 1% of the tubes in the sample studied could be filled in this way. Here we report that heating in carbon dioxide gas can result in the partial or complete destruction of the tube caps and stripping of the outer layers te produce thinner tubes. In some cases, we have thinned the extremity of tubes to a single layer. The opened tubes can be regarded as nanoscale test-tubes for adsorption of other molecules, and this controlled method of thinning may allow studies of the properties of single tubes. |
| first_indexed | 2024-03-06T18:18:44Z |
| format | Journal article |
| id | oxford-uuid:05896d27-a5da-4b47-bccd-c0b78fc43854 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:18:44Z |
| publishDate | 1993 |
| record_format | dspace |
| spelling | oxford-uuid:05896d27-a5da-4b47-bccd-c0b78fc438542022-03-26T08:57:44ZThinning and opening of carbon nanotubes by oxidation using carbon dioxideJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:05896d27-a5da-4b47-bccd-c0b78fc43854EnglishSymplectic Elements at Oxford1993Tsang, SHarris, PGreen, MThe discovery1 and bulk synthesis2 of carbon nanotubes has stimulated great interest. It has been suggested that these structures may have useful electronic3-5 and mechanical6 properties, and these might be modified by introducing foreign materials into the nanotubes. But the tubes are invariably capped at the ends. Ajayan and Iijima7 have succeeded in drawing molten material (lead or one of its compounds) into the tubes by heating them in the presence of lead and oxygen; less than 1% of the tubes in the sample studied could be filled in this way. Here we report that heating in carbon dioxide gas can result in the partial or complete destruction of the tube caps and stripping of the outer layers te produce thinner tubes. In some cases, we have thinned the extremity of tubes to a single layer. The opened tubes can be regarded as nanoscale test-tubes for adsorption of other molecules, and this controlled method of thinning may allow studies of the properties of single tubes. |
| spellingShingle | Tsang, S Harris, P Green, M Thinning and opening of carbon nanotubes by oxidation using carbon dioxide |
| title | Thinning and opening of carbon nanotubes by oxidation using carbon dioxide |
| title_full | Thinning and opening of carbon nanotubes by oxidation using carbon dioxide |
| title_fullStr | Thinning and opening of carbon nanotubes by oxidation using carbon dioxide |
| title_full_unstemmed | Thinning and opening of carbon nanotubes by oxidation using carbon dioxide |
| title_short | Thinning and opening of carbon nanotubes by oxidation using carbon dioxide |
| title_sort | thinning and opening of carbon nanotubes by oxidation using carbon dioxide |
| work_keys_str_mv | AT tsangs thinningandopeningofcarbonnanotubesbyoxidationusingcarbondioxide AT harrisp thinningandopeningofcarbonnanotubesbyoxidationusingcarbondioxide AT greenm thinningandopeningofcarbonnanotubesbyoxidationusingcarbondioxide |