Contrasting photochemical and thermal reactivity of Ru(CO)2(PPh3)(dppe) towards hydrogen rationalised by parahydrogen NMR and DFT studies.

Contrasting photochemical and thermal reactivity of Ru(CO)2(PPh3)(dppe) towards hydrogen rationalised by parahydrogen NMR and DFT studies.

The synthesis, characterisation and thermal and photochemical reactivity of Ru(CO)2(PPh3)(dppe) 1 towards hydrogen are described. Compound proved to exist in both fac (major) and mer forms in solution. Under thermal conditions, PPh3 is lost from 1 in the major reaction pathway and the known complex...

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Bibliographic Details
Main Authors:	Blazina, D, Dunne, J, Aiken, S, Duckett, S, Elkington, C, McGrady, J, Poli, R, Walton, S, Anwar, MS, Jones, J, Carteret, H
Format:	Journal article
Language:	English
Published:	2006

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