Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates
An investigation of catalysis and ligand exchange in the arylation of nucleophiles with phenylboronic acid and mixed ligand lead(IV) complexes is described. Although this reaction is known to be catalyzed by mercury(II) acetate, other heavy metals have been shown to have a similar effect, albeit les...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1998
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| _version_ | 1797051683437543424 |
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| author | Moloney, M Paul, DR Thompson, R Wright, E |
| author_facet | Moloney, M Paul, DR Thompson, R Wright, E |
| author_sort | Moloney, M |
| collection | OXFORD |
| description | An investigation of catalysis and ligand exchange in the arylation of nucleophiles with phenylboronic acid and mixed ligand lead(IV) complexes is described. Although this reaction is known to be catalyzed by mercury(II) acetate, other heavy metals have been shown to have a similar effect, albeit less efficiently. The effect of pyridine has been investigated with a range of chelating ligands containing a pyridine sub-unit. |
| first_indexed | 2024-03-06T18:23:01Z |
| format | Journal article |
| id | oxford-uuid:06f494fa-f7a6-4120-9a44-ea3ad8bce4a0 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:23:01Z |
| publishDate | 1998 |
| record_format | dspace |
| spelling | oxford-uuid:06f494fa-f7a6-4120-9a44-ea3ad8bce4a02022-03-26T09:05:08ZLigand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylatesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:06f494fa-f7a6-4120-9a44-ea3ad8bce4a0EnglishSymplectic Elements at Oxford1998Moloney, MPaul, DRThompson, RWright, EAn investigation of catalysis and ligand exchange in the arylation of nucleophiles with phenylboronic acid and mixed ligand lead(IV) complexes is described. Although this reaction is known to be catalyzed by mercury(II) acetate, other heavy metals have been shown to have a similar effect, albeit less efficiently. The effect of pyridine has been investigated with a range of chelating ligands containing a pyridine sub-unit. |
| spellingShingle | Moloney, M Paul, DR Thompson, R Wright, E Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates |
| title | Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates |
| title_full | Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates |
| title_fullStr | Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates |
| title_full_unstemmed | Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates |
| title_short | Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates |
| title_sort | ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates |
| work_keys_str_mv | AT moloneym ligandexchangeandcatalysisinphenylationreactionsmediatedbyleadtetracarboxylates AT pauldr ligandexchangeandcatalysisinphenylationreactionsmediatedbyleadtetracarboxylates AT thompsonr ligandexchangeandcatalysisinphenylationreactionsmediatedbyleadtetracarboxylates AT wrighte ligandexchangeandcatalysisinphenylationreactionsmediatedbyleadtetracarboxylates |