Mechanistic Study of a Ru-Xantphos Catalyst for Tandem Alcohol Dehydrogenation and Reductive Aryl-Ether Cleavage

Mechanistic Study of a Ru-Xantphos Catalyst for Tandem Alcohol Dehydrogenation and Reductive Aryl-Ether Cleavage

We employ density functional theory (DFT) calculations and kinetics measurements to understand the mechanism of a xantphos-containing molecular ruthenium catalyst acting on an alkyl aryl ether linkage similar to that found in lignin to produce acetophenone and phenol. The most favorable reaction pat...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron:	Chmely, S, Kim, S, Ciesielski, P, Jimenez-Oses, G, Paton, R, Beckham, G
Fformat:	Journal article
Iaith:	English
Cyhoeddwyd:	2013

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