$Copper(I) O,O '-dialkyldithiophosphate clusters: EXAFS, NMR and X-ray diffraction studies$

Copper(I) O,O '-dialkyldithiophosphate clusters: EXAFS, NMR and X-ray diffraction studies

Copper K-edge EXAFS data for six polycrystalline cubic cluster compounds, {Cu8[S2P(OR)2]6(μ8-S)} with R = Et, nPr, iPr, nBu, iBu and iAm, show that the architecture of their Cu8(S2P)2S cores is fairly rigid and independent of both length and branching of the alkyl chain, and that the structure of th...

书目详细资料
Main Authors:	Rusanova, D, Christensen, K, Persson, I, Pike, K, Antzutkin, O, Zou, X, Dupree, R, Forsling, W
格式:	Journal article
语言:	English
出版:	2007

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