$Copper(I) O,O '-dialkyldithiophosphate clusters: EXAFS, NMR and X-ray diffraction studies$

Copper(I) O,O '-dialkyldithiophosphate clusters: EXAFS, NMR and X-ray diffraction studies

Copper K-edge EXAFS data for six polycrystalline cubic cluster compounds, {Cu8[S2P(OR)2]6(μ8-S)} with R = Et, nPr, iPr, nBu, iBu and iAm, show that the architecture of their Cu8(S2P)2S cores is fairly rigid and independent of both length and branching of the alkyl chain, and that the structure of th...

Полное описание

Библиографические подробности
Главные авторы:	Rusanova, D, Christensen, K, Persson, I, Pike, K, Antzutkin, O, Zou, X, Dupree, R, Forsling, W
Формат:	Journal article
Язык:	English
Опубликовано:	2007

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