Alkene ozonolysis in the presence of diazo functionality: accessing an intermediate for squalestatin synthesis
Studies on both the propensity for intramolecular cycloaddition between diazo and alkene functionality, and the tolerance of α-substituted α-diazoesters towards ozone in the presence of an alkene, led to chemoselective alkene ozonolysis of an ε-unsaturated-α-diazoester to give a key racemic diazoket...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Thieme Gruppe
2019
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