Intramolecular C-C agostic complexes: C-C sigma interactions by another name.
In this comprehensive review the developments in the synthesis, characterization and reactivity of complexes (s-, d- and f-block) in which a C-C single bond interacts with a metal centre are discussed: so called C-CM agostic complexes. Such species are of significant interest with regard to structur...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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2014
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| _version_ | 1797051974984663040 |
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| author | Etienne, M Weller, A |
| author_facet | Etienne, M Weller, A |
| author_sort | Etienne, M |
| collection | OXFORD |
| description | In this comprehensive review the developments in the synthesis, characterization and reactivity of complexes (s-, d- and f-block) in which a C-C single bond interacts with a metal centre are discussed: so called C-CM agostic complexes. Such species are of significant interest with regard to structure and bonding, the activation of C-C single bonds and, thus, catalytic methods of C-C bond formation (or activation). Examples of C-C agostic complexes of early and later transition metals, actinides and group 1 metals are discussed, along with C-C agostic interactions in metallacyclobutanes. Examples of Si-Si∙∙∙M, B-C∙∙∙M and B-B∙∙∙M agostic interactions are also presented. Throughout, the structural, spectroscopic and computational markers that indicate the likely presence of a C-C∙∙∙M agostic interaction in a complex are highlighted. |
| first_indexed | 2024-03-06T18:26:42Z |
| format | Journal article |
| id | oxford-uuid:0838c469-3417-447b-b0d4-5db3e0bb7d16 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:26:42Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | oxford-uuid:0838c469-3417-447b-b0d4-5db3e0bb7d162022-03-26T09:11:40ZIntramolecular C-C agostic complexes: C-C sigma interactions by another name.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0838c469-3417-447b-b0d4-5db3e0bb7d16EnglishSymplectic Elements at Oxford2014Etienne, MWeller, AIn this comprehensive review the developments in the synthesis, characterization and reactivity of complexes (s-, d- and f-block) in which a C-C single bond interacts with a metal centre are discussed: so called C-CM agostic complexes. Such species are of significant interest with regard to structure and bonding, the activation of C-C single bonds and, thus, catalytic methods of C-C bond formation (or activation). Examples of C-C agostic complexes of early and later transition metals, actinides and group 1 metals are discussed, along with C-C agostic interactions in metallacyclobutanes. Examples of Si-Si∙∙∙M, B-C∙∙∙M and B-B∙∙∙M agostic interactions are also presented. Throughout, the structural, spectroscopic and computational markers that indicate the likely presence of a C-C∙∙∙M agostic interaction in a complex are highlighted. |
| spellingShingle | Etienne, M Weller, A Intramolecular C-C agostic complexes: C-C sigma interactions by another name. |
| title | Intramolecular C-C agostic complexes: C-C sigma interactions by another name. |
| title_full | Intramolecular C-C agostic complexes: C-C sigma interactions by another name. |
| title_fullStr | Intramolecular C-C agostic complexes: C-C sigma interactions by another name. |
| title_full_unstemmed | Intramolecular C-C agostic complexes: C-C sigma interactions by another name. |
| title_short | Intramolecular C-C agostic complexes: C-C sigma interactions by another name. |
| title_sort | intramolecular c c agostic complexes c c sigma interactions by another name |
| work_keys_str_mv | AT etiennem intramolecularccagosticcomplexesccsigmainteractionsbyanothername AT wellera intramolecularccagosticcomplexesccsigmainteractionsbyanothername |