Silver phosphanes partnered with carborane monoanions: synthesis, structures and use as highly active Lewis acid catalysts in a hetero-Diels-Alder reaction.
Four Lewis acidic silver phosphane complexes partnered with [1-closo-CB(11)H(12)](-) and [1-closo-CB(11)H(6)Br(6)](-) have been synthesised and studied by solution NMR and solid-state X-ray diffraction techniques. In the complex [Ag(PPh(3))(CB(11)H(12))] (1), the silver is coordinated with the carbo...
Päätekijät: | Patmore, N, Hague, C, Cotgreave, J, Mahon, M, Frost, C, Weller, A |
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Aineistotyyppi: | Journal article |
Kieli: | English |
Julkaistu: |
2002
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