Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine.
N-tert-Butylsulfonyl and N-tert-butylsulfinyl aziridine undergo alpha-lithiation/electrophile trapping providing a new entry to terminal aziridines. With N-tert-butylsulfinyl aziridine complete asymmetric induction is observed alpha to nitrogen.
| Prif Awduron: | , , , |
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| Fformat: | Journal article |
| Iaith: | English |
| Cyhoeddwyd: |
2008
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| _version_ | 1826258086178848768 |
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| author | Hodgson, D Hughes, S Thompson, A Heightman, T |
| author_facet | Hodgson, D Hughes, S Thompson, A Heightman, T |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | N-tert-Butylsulfonyl and N-tert-butylsulfinyl aziridine undergo alpha-lithiation/electrophile trapping providing a new entry to terminal aziridines. With N-tert-butylsulfinyl aziridine complete asymmetric induction is observed alpha to nitrogen. |
| first_indexed | 2024-03-06T18:28:27Z |
| format | Journal article |
| id | oxford-uuid:08cbb4b3-0f70-493e-b7c2-78ef9724c9fe |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:28:27Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:08cbb4b3-0f70-493e-b7c2-78ef9724c9fe2022-03-26T09:14:50ZTerminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:08cbb4b3-0f70-493e-b7c2-78ef9724c9feEnglishSymplectic Elements at Oxford2008Hodgson, DHughes, SThompson, AHeightman, TN-tert-Butylsulfonyl and N-tert-butylsulfinyl aziridine undergo alpha-lithiation/electrophile trapping providing a new entry to terminal aziridines. With N-tert-butylsulfinyl aziridine complete asymmetric induction is observed alpha to nitrogen. |
| spellingShingle | Hodgson, D Hughes, S Thompson, A Heightman, T Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine. |
| title | Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine. |
| title_full | Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine. |
| title_fullStr | Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine. |
| title_full_unstemmed | Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine. |
| title_short | Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine. |
| title_sort | terminal aziridines by alpha deprotonation electrophile trapping of n protected aziridine |
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