A β-diketiminate-stabilized sila-acyl chloride: systematic access to base-stabilized silicon analogues of classical carbonyl compounds
An oxidation/substitution strategy for the synthesis of silicon analogues of classical organic carbonyl compounds is reported, by making use of a novel β-diketiminate-supported sila-acyl chloride-the first example of such a compound isolated without the use of a stabilizing Lewis acid. Nucleophilic...
Main Authors: | Do, D, Protchenko, A, Ángeles Fuentes, M, Hicks, J, Kolychev, E, Vasko, P, Aldridge, S |
---|---|
Format: | Journal article |
Language: | English |
Published: |
Wiley
2018
|
Similar Items
-
N‐nacnac stabilized tetrelenes: formation of an N,P‐Heterocyclic germylene via C–C bond Insertion
by: Do, D, et al.
Published: (2018) -
On the viability of catalytic turnover via Al-O/B-H metathesis: The reactivity of β-diketiminate aluminium hydrides towards CO2 and boranes
by: Caise, A, et al.
Published: (2018) -
N-nacnac stabilized tetrylenes: access to silicon hydride systems via migration processes
by: Cao Huan Do, D, et al.
Published: (2021) -
Successive rotonation of an N‐heterocyclic imine derived carbonyl: Superelectrophilic dication versus masked acylium ion
by: Loh, Y, et al.
Published: (2018) -
Acid-base free main group carbonyl analogues
by: Loh, YK, et al.
Published: (2020)