Palladium-catalyzed substitution of allylic fluorides.
As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladium-catalyzed substitution. Their activity towards this reaction fits in the series OCO(2)Me>OBz>>F>>OAc. The classic stereoretention mechanism that involves se...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2009
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| _version_ | 1826258433730412544 |
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| author | Hazari, A Gouverneur, V Brown, J |
| author_facet | Hazari, A Gouverneur, V Brown, J |
| author_sort | Hazari, A |
| collection | OXFORD |
| description | As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladium-catalyzed substitution. Their activity towards this reaction fits in the series OCO(2)Me>OBz>>F>>OAc. The classic stereoretention mechanism that involves sequential inversions does not operate in this case. Several distinct cases are considered. |
| first_indexed | 2024-03-06T18:33:56Z |
| format | Journal article |
| id | oxford-uuid:0a976d5e-4611-4d7c-bca1-a6e57cd09bc4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:33:56Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:0a976d5e-4611-4d7c-bca1-a6e57cd09bc42022-03-26T09:24:39ZPalladium-catalyzed substitution of allylic fluorides.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0a976d5e-4611-4d7c-bca1-a6e57cd09bc4EnglishSymplectic Elements at Oxford2009Hazari, AGouverneur, VBrown, JAs unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladium-catalyzed substitution. Their activity towards this reaction fits in the series OCO(2)Me>OBz>>F>>OAc. The classic stereoretention mechanism that involves sequential inversions does not operate in this case. Several distinct cases are considered. |
| spellingShingle | Hazari, A Gouverneur, V Brown, J Palladium-catalyzed substitution of allylic fluorides. |
| title | Palladium-catalyzed substitution of allylic fluorides. |
| title_full | Palladium-catalyzed substitution of allylic fluorides. |
| title_fullStr | Palladium-catalyzed substitution of allylic fluorides. |
| title_full_unstemmed | Palladium-catalyzed substitution of allylic fluorides. |
| title_short | Palladium-catalyzed substitution of allylic fluorides. |
| title_sort | palladium catalyzed substitution of allylic fluorides |
| work_keys_str_mv | AT hazaria palladiumcatalyzedsubstitutionofallylicfluorides AT gouverneurv palladiumcatalyzedsubstitutionofallylicfluorides AT brownj palladiumcatalyzedsubstitutionofallylicfluorides |