Palladium-catalyzed substitution of allylic fluorides.

As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladium-catalyzed substitution. Their activity towards this reaction fits in the series OCO(2)Me>OBz>>F>>OAc. The classic stereoretention mechanism that involves se...

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Hlavní autoři: Hazari, A, Gouverneur, V, Brown, J
Médium: Journal article
Jazyk:English
Vydáno: 2009