Palladium-catalyzed substitution of allylic fluorides.

Palladium-catalyzed substitution of allylic fluorides.

As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladium-catalyzed substitution. Their activity towards this reaction fits in the series OCO(2)Me>OBz>>F>>OAc. The classic stereoretention mechanism that involves se...

Full description

Bibliographic Details
Main Authors:	Hazari, A, Gouverneur, V, Brown, J
Format:	Journal article
Language:	English
Published:	2009

Similar Items

Platinum-catalyzed substitution of allylic fluorides
by: Benedetto, E, et al.
Published: (2012)

Platinum-Catalyzed Substitution of Allylic Fluorides
by: Benedetto, E, et al.
Published: (2012)

Palladium-catalyzed allylic fluorination.
by: Hollingworth, C, et al.
Published: (2011)

Palladium catalyzed allylic fluorination
by: Hollingworth, C, et al.
Published: (2012)

Palladium-catalyzed substitution and cross-coupling of benzylic fluorides.
by: Blessley, G, et al.
Published: (2012)

Preparation of Allylic Fluorides
by: Gouverneur, V, et al.
Published: (2012)

Palladium-catalyzed allylic alkylation of enamides and allylic acetates
by: Lim, Juan Mei
Published: (2012)

The chemistry of propargylic and allylic fluorides.
by: Pacheco, M, et al.
Published: (2008)

Stereoselective synthesis of internal allylic fluorides.
by: Thibaudeau, S, et al.
Published: (2004)

Regio- and enantioselective synthesis of allylic fluorides by electrophilic fluorodesilylation of allyl silanes.
by: Greedy, B, et al.
Published: (2003)

The Reaction of Carbon Dioxide with Palladium-Allyl Bonds
by: Wu, J, et al.
Published: (2010)

Nickel-Catalyzed Allylic Substitution of Simple Alkenes
by: Matsubara, Ryosuke, et al.
Published: (2012)

Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
by: Ding, Wei-Jie, et al.
Published: (2024)

Electrophilic fluorodesilylation of allylsilanes: A mild synthetic route to allylic fluorides.
by: Greedy, B, et al.
Published: (2002)

Regio- and stereoretentive synthesis of branched, linear (E)- and (Z)-allyl fluorides from allyl carbonates under Ir-catalysis
by: Benedetto, E, et al.
Published: (2013)

β-type glycosidic bond formation by palladium-catalyzed decarboxylative allylation
by: Xiang, Shaohua, et al.
Published: (2015)

Fluorous synthesis of allylic fluorides: C-F bond formation as the detagging process.
by: Boldon, S, et al.
Published: (2008)

Palladium-catalyzed directed meta-selective C-H allylation of arenes: unactivated internal olefins as allyl surrogates
by: Achar, T, et al.
Published: (2019)

Sequential cross-metathesis/electrophilic fluorodesilylation: a novel entry to functionalized allylic fluorides.
by: Thibaudeau, S, et al.
Published: (2003)

Palladium mediated allylic fluorination
by: Hollingworth, C
Published: (2013)

Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
by: Geurts, K, et al.
Published: (2008)

One-pot palladium-catalyzed synthesis of sulfonyl fluorides from aryl bromides
by: Davies, A, et al.
Published: (2016)

Synthesis of 3-fluoropyrrolidines and 4-fluoropyrrolidin-2-ones from allylic fluorides.
by: Combettes, L, et al.
Published: (2012)

Cyclic alkenylsulfonyl fluorides: palladium‐catalyzed synthesis and functionalization of compact multifunctional reagents
by: Lou, TSB, et al.
Published: (2019)

Cyclic alkenylsulfonyl fluorides: palladium-catalyzed synthesis and functionalization of compact multi-functional reagents
by: Lou, T, et al.
Published: (2019)

Synthesis of substituted isoquinolines utilizing palladium-catalyzed α-arylation of ketones.
by: Donohoe, T, et al.
Published: (2012)

Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
by: Ding, Feiqing, et al.
Published: (2013)

Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation : formal synthesis of aspergillide A
by: Xiang, Shaohua, et al.
Published: (2014)

Palladium-catalyzed oxidative cyclizations: synthesis of dihydropyranones and furanones.
by: Reiter, M, et al.
Published: (2005)

Iridium-catalyzed reductive allylation of esters
by: Xie, L, et al.
Published: (2019)

Synthesis and reactivity of allylic fluorides under transition metal catalysis
by: Benedetto, E
Published: (2013)

Palladacycle-catalyzed tandem allylic amination/allylation protocol for one-pot synthesis of 2-allylanilines from allylic alcohols
by: Chen, Ke, et al.
Published: (2013)

Evaluation of palladium substitutes for gold /
by: 187107 Graham, A. H., et al.

Palladium-catalyzed asymmetric allylic alkylations of colby pro-enolates with MBH carbonates : enantioselective access to quaternary C-F oxindoles
by: Zhu, Yi, et al.
Published: (2020)

Triflic-acid-catalyzed tandem allylic substitution–cyclization reaction of alcohols with thiophenols—facile access to polysubstituted thiochromans
by: Abdul Sadeer, et al.
Published: (2019)

Synthesis and synthetic applications of allylic monofluorides
by: Pacheco, M, et al.
Published: (2006)

Facile access to cis-2,6-disubstituted tetrahydropyrans by palladium-catalyzed decarboxylative allylation : total syntheses of (±)-centrolobine and (+)-decytospolides A and B
by: Zeng, Jing, et al.
Published: (2014)

Alkaline-earth metal catalyzed dehydrative allylic alkylation
by: Xie, Peizhong, et al.
Published: (2022)

Copper catalyzed asymmetric synthesis of chiral allylic esters.
by: Geurts, K, et al.
Published: (2006)

Linear allylic halides in metal-catalysed asymmetric substitutions
by: Mistry, N
Published: (2018)