Formate adsorption on Pt nanoparticles during formic acid electro-oxidation: insights from in situ infrared spectroscopy

Formate adsorption on Pt nanoparticles during formic acid electro-oxidation: insights from in situ infrared spectroscopy

Adsorbed formate is observed on a supported Pt nanoparticle for the first time during formic acid electro-oxidation. Bands assigned to OCO stretching and CH bending reveal some OCO but little CH bond weakening on adsorption compared to the free anion. The formate potential dependence i...

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Bibliographic Details
Main Authors:	McPherson, I, Ash, P, Jacobs, R, Vincent, K
Format:	Journal article
Published:	Royal Society of Chemistry 2016

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