Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.

The electron transfer kinetics associated with both the reduction of oxygen and of protons to form hydrogen at gold nanoparticles are shown to display strong retardation when studied at citrate capped ultra small (2 nm) gold nanoparticles. Negative nanocatalysis in the hydrogen evolution reaction (H...

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Main Authors: Wang, Y, Laborda, E, Tschulik, K, Damm, C, Molina, A, Compton, R
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2014
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author Wang, Y
Laborda, E
Tschulik, K
Damm, C
Molina, A
Compton, R
author_facet Wang, Y
Laborda, E
Tschulik, K
Damm, C
Molina, A
Compton, R
author_sort Wang, Y
collection OXFORD
description The electron transfer kinetics associated with both the reduction of oxygen and of protons to form hydrogen at gold nanoparticles are shown to display strong retardation when studied at citrate capped ultra small (2 nm) gold nanoparticles. Negative nanocatalysis in the hydrogen evolution reaction (HER) is reported for the first time.
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spelling oxford-uuid:0ba6d5e6-f1ba-4580-8799-ac15dea59edf2022-03-26T09:30:39ZStrong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0ba6d5e6-f1ba-4580-8799-ac15dea59edfEnglishSymplectic Elements at OxfordRoyal Society of Chemistry2014Wang, YLaborda, ETschulik, KDamm, CMolina, ACompton, RThe electron transfer kinetics associated with both the reduction of oxygen and of protons to form hydrogen at gold nanoparticles are shown to display strong retardation when studied at citrate capped ultra small (2 nm) gold nanoparticles. Negative nanocatalysis in the hydrogen evolution reaction (HER) is reported for the first time.
spellingShingle Wang, Y
Laborda, E
Tschulik, K
Damm, C
Molina, A
Compton, R
Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.
title Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.
title_full Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.
title_fullStr Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.
title_full_unstemmed Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.
title_short Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles.
title_sort strong negative nanocatalysis oxygen reduction and hydrogen evolution at very small 2 nm gold nanoparticles
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AT labordae strongnegativenanocatalysisoxygenreductionandhydrogenevolutionatverysmall2nmgoldnanoparticles
AT tschulikk strongnegativenanocatalysisoxygenreductionandhydrogenevolutionatverysmall2nmgoldnanoparticles
AT dammc strongnegativenanocatalysisoxygenreductionandhydrogenevolutionatverysmall2nmgoldnanoparticles
AT molinaa strongnegativenanocatalysisoxygenreductionandhydrogenevolutionatverysmall2nmgoldnanoparticles
AT comptonr strongnegativenanocatalysisoxygenreductionandhydrogenevolutionatverysmall2nmgoldnanoparticles