Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides.
The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti S(E)2' mechanism for the flu...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2008
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| _version_ | 1797053057326907392 |
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| author | Carroll, L McCullough, S Rees, T Claridge, T Gouverneur, V |
| author_facet | Carroll, L McCullough, S Rees, T Claridge, T Gouverneur, V |
| author_sort | Carroll, L |
| collection | OXFORD |
| description | The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti S(E)2' mechanism for the fluorination step. |
| first_indexed | 2024-03-06T18:38:47Z |
| format | Journal article |
| id | oxford-uuid:0c2f744b-68bc-4055-bbae-c333efd95614 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:38:47Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:0c2f744b-68bc-4055-bbae-c333efd956142022-03-26T09:33:40ZStereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0c2f744b-68bc-4055-bbae-c333efd95614EnglishSymplectic Elements at Oxford2008Carroll, LMcCullough, SRees, TClaridge, TGouverneur, VThe electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti S(E)2' mechanism for the fluorination step. |
| spellingShingle | Carroll, L McCullough, S Rees, T Claridge, T Gouverneur, V Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides. |
| title | Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides. |
| title_full | Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides. |
| title_fullStr | Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides. |
| title_full_unstemmed | Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides. |
| title_short | Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides. |
| title_sort | stereospecific anti se2 fluorination of allenylsilanes synthesis of enantioenriched propargylic fluorides |
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