Thermodynamics of binding of carboxylates to amphiphilic Eu(3+)/Cu(2+) metallacrown.
The binding constants of acetate and benzoate to a Pheha-based 15-metallacrown-5 have been determined by a fluorimetric indicator displacement assay demonstrating on a thermodynamic basis the stabilization effect arising from complexation of the less polar carboxylate into the hydrophobic pocket of...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2009
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