PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES
Helium-(I) and -(II) excited photoelectron spectra of the metal tetrakis(tetrahydroborates) M(BH4)4 (M = Zr, Hf, or U) and the He(I) spectrum of Al(BH4)3 are reported. A simple molecular-orbital model is developed to account for features in the spectra associated with ligand ionizations. Final-state...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1978
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| _version_ | 1797053624655806464 |
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| author | Downs, A Thomas, P Orchard, A Egdell, R |
| author_facet | Downs, A Thomas, P Orchard, A Egdell, R |
| author_sort | Downs, A |
| collection | OXFORD |
| description | Helium-(I) and -(II) excited photoelectron spectra of the metal tetrakis(tetrahydroborates) M(BH4)4 (M = Zr, Hf, or U) and the He(I) spectrum of Al(BH4)3 are reported. A simple molecular-orbital model is developed to account for features in the spectra associated with ligand ionizations. Final-state structure and cross-section variations for the outermost metal f subshells in U(BH4)4 and Hf(BH4)4 are discussed in relation to the expected atomic behaviour. |
| first_indexed | 2024-03-06T18:46:16Z |
| format | Journal article |
| id | oxford-uuid:0ea26624-370a-4171-a20b-76c858619fda |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:46:16Z |
| publishDate | 1978 |
| record_format | dspace |
| spelling | oxford-uuid:0ea26624-370a-4171-a20b-76c858619fda2022-03-26T09:46:53ZPHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0ea26624-370a-4171-a20b-76c858619fdaEnglishSymplectic Elements at Oxford1978Downs, AThomas, POrchard, AEgdell, RHelium-(I) and -(II) excited photoelectron spectra of the metal tetrakis(tetrahydroborates) M(BH4)4 (M = Zr, Hf, or U) and the He(I) spectrum of Al(BH4)3 are reported. A simple molecular-orbital model is developed to account for features in the spectra associated with ligand ionizations. Final-state structure and cross-section variations for the outermost metal f subshells in U(BH4)4 and Hf(BH4)4 are discussed in relation to the expected atomic behaviour. |
| spellingShingle | Downs, A Thomas, P Orchard, A Egdell, R PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES |
| title | PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES |
| title_full | PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES |
| title_fullStr | PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES |
| title_full_unstemmed | PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES |
| title_short | PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES |
| title_sort | photoelectron spectra of metal tetrahydroborates |
| work_keys_str_mv | AT downsa photoelectronspectraofmetaltetrahydroborates AT thomasp photoelectronspectraofmetaltetrahydroborates AT orcharda photoelectronspectraofmetaltetrahydroborates AT egdellr photoelectronspectraofmetaltetrahydroborates |