Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity.
(Figure Presented) Variations in the formal electrochemical potential (E 0) and electron-transfer rates (K 0) of the blue copper protein azurin have been directly observed. A new method, fluorescent cyclic voltammetry (FCV), was used to resolve the pro...
| Главные авторы: | , , , , , , , , , |
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| Формат: | Journal article |
| Язык: | English |
| Опубликовано: |
2010
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| _version_ | 1826259523632889856 |
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| author | Salverda, J Patil, A Mizzon, G Kuznetsova, S Zauner, G Akkilic, N Canters, G Davis, J Heering, H Aartsma, T |
| author_facet | Salverda, J Patil, A Mizzon, G Kuznetsova, S Zauner, G Akkilic, N Canters, G Davis, J Heering, H Aartsma, T |
| author_sort | Salverda, J |
| collection | OXFORD |
| description | (Figure Presented) Variations in the formal electrochemical potential (E 0) and electron-transfer rates (K 0) of the blue copper protein azurin have been directly observed. A new method, fluorescent cyclic voltammetry (FCV), was used to resolve the properties of 100-1000 proteins. On this scale, the presence of large variations in the values of both E 0 and k 0 could be established and several forms of heterogeneity were differentiated. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-06T18:51:14Z |
| format | Journal article |
| id | oxford-uuid:104d8448-1b59-4f31-a127-288d5d6a3620 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:51:14Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:104d8448-1b59-4f31-a127-288d5d6a36202022-03-26T09:55:46ZFluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:104d8448-1b59-4f31-a127-288d5d6a3620EnglishSymplectic Elements at Oxford2010Salverda, JPatil, AMizzon, GKuznetsova, SZauner, GAkkilic, NCanters, GDavis, JHeering, HAartsma, T(Figure Presented) Variations in the formal electrochemical potential (E 0) and electron-transfer rates (K 0) of the blue copper protein azurin have been directly observed. A new method, fluorescent cyclic voltammetry (FCV), was used to resolve the properties of 100-1000 proteins. On this scale, the presence of large variations in the values of both E 0 and k 0 could be established and several forms of heterogeneity were differentiated. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | Salverda, J Patil, A Mizzon, G Kuznetsova, S Zauner, G Akkilic, N Canters, G Davis, J Heering, H Aartsma, T Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity. |
| title | Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity. |
| title_full | Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity. |
| title_fullStr | Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity. |
| title_full_unstemmed | Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity. |
| title_short | Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity. |
| title_sort | fluorescent cyclic voltammetry of immobilized azurin direct observation of thermodynamic and kinetic heterogeneity |
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