The role of substrate in unmasking oxyl character in oxomanganese complexes: the key to selectivity?
The reaction profile for sulfide oxidation by formally Mn(V)=O species depends critically on the electronic structure of the isolated oxidant. In cases where the ground state has dominant oxyl radical character, the oxidation occurs in sequential one-electron steps, the first of which is barrierless...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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